Hazmat Placards and UN Numbers: What You Need to Know

Have you ever seen a truck, railcar, container or large tanks at a tank farm and wondered what types of chemicals it was transporting or storing? The answer can be found in its UN numbers and hazmat placards.

What Are UN Numbers?

Located on the back or sides of trailers or other containers, UN numbers (or UN IDs) are four-digit numbers ranging from 0004-3534 that identify dangerous goods or hazardous substances — such as explosives, flammable liquids, or toxic substances — in the framework of international transport.

These numbers are assigned by the United Nations (UN) Committee of Experts on the Transport of Dangerous Goods, and must be listed on the Material Safety Data Sheet (MSDS) of each shipment. (Goods that aren’t classified or regulated by the UN are given four-digit North American (NA) numbers ranging from 8000-9279. These numbers are designated by the United States Department of Transportation (DOT).)

What Are Hazmat Placards?

In addition to a UN number, the DOT requires cargo to carry Hazmat placards that help shippers determine its class, division, and compatibility group.

Similar to road or construction signs, these diamond-shaped hazmat placards alert the public that potentially hazardous materials are being hauled, as well as inform emergency responders which chemicals are present in case of an accident. Even if members of the public or first responders are unaware of exactly which materials are on board, the presence of hazmat placards lets them know that they should proceed with caution.

With rare exceptions, companies that transport hazardous materials without the use of DOT hazmat placards are at risk for stiff fines and other penalties.

UN Hazmat Sign Components and Classifications

It’s vital that anyone who works with or around hazardous materials can properly identify the various aspects of each hazmat placard, as well as the various classifications that each one represents.

CLASSIFICATIONS

Hazmat warning placards are broken down into nine different classifications, along with their divisions. Each class number is found at the bottom of the sign, while the division number can be found in the middle.

COMPONENTS

Each hazmat sign has up to six main parts:

1. Hazard classification number — See below.
2. UN/NA number — See above.
3. Compatibility letters — Some placards include the letters A-S, which let shippers and carriers know which explosive materials can be loaded together onto a trailer.
4. Color — Other than classification numbers, hazmat placards are most easily identified by their different colors.
   • Orange represents explosive materials, including products like dynamite, ammunition, or fireworks.
   • Red represents flammable goods like gasoline, rubbing alcohol, paint, or acetone.
   • Green signs signify non-flammable substances like compressed or liquefied gases.
   • Yellow indicates the transport of oxidizers — like ammonium nitrate, potassium nitrate, or nitric acid — that are likely to combust when mixed with oxygen.
   • White represents poisonous and bio-hazardous substances like dyes, aerosols, acids, and medical waste.
   • Blue signifies materials that can become flammable when combined with water, like sodium, calcium, and potassium.
   • A half red and white sign indicates the presence of substances that can ignite when exposed to air, like aluminum and lithium alkyls or white phosphorous.
   • Red and white stripes indicate flammable solids such as matches and magnesium.
   • Red and yellow indicate organic peroxides that can ignite or explode, including methyl ethyl ketone peroxide and benzoyl peroxide.
   • Yellow and white represent radioactive substances often found in medical equipment.
   • Half white and half black indicates corrosive materials that can irritate and harm the skin, including batteries, hydrochloric acid, sulfuric acid, and sodium hydroxide.
   • White with black vertical stripes denote various dangerous goods, including nonclassified, environmentally hazardous substances like asbestos and dry ice.

5. Words — Depending on the contents of each container, its hazmat placard is labeled with various terms like “Spontaneously Combustible,” “Explosive,” “Nonflammable Gas,” “Oxygen,” “Poison,” “Flammable,” and others.
6. Graphics — Different hazmat placards feature illustrations to reinforce the danger of their contents. For example, placards for toxic materials include an image of a skull and crossbones, while signs for radioactive materials include a radiation symbol consisting of three blades surrounding a small circle.

Rules for Placement

According to federal regulations, each freight container, railcar, transport vehicle, or other vessel carrying hazardous materials must display placards on each side and each end. Regulations also state that placards on railcars and transport vehicles must be clearly visible from the direction they face unless they are obscured when coupled with another railcar or transport vehicle.

In all, carriers must display at least four placards in areas where the view isn’t obstructed. Some carriers add extra signs on each side of the truck cab for additional visibility.

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Common chemical transportation placards.

Acetic Acid

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Acetic Anhydride

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Acetonitrile

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Acrolein

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Acrylic Acid

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Acrylonitrile

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Aluminum Chloride

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Aluminum Sulfate

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Ammonia

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Ammonium Hydroxide

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Ammonium Nitrate

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Aniline

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Benzene

Benzene handling design & loading

Benzyl Chloride

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Bromotrifluoro methane

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Butadiene

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Carbon Dioxide

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Caustic

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Chlorine

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Chloroform

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Chlorosulfonic Acid

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DMH

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Diethylene Glycol

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Dodecylbenzene Sulfonic Acid

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Ethanol

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Ethyl Acetate

Ethyl Acetate handling design & loading

Ethyl Chloride

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Ethylene

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Ethylene Dichloride

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Ethylene Oxide

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Ethylene Glycol

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Ferric Chloride

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Ferrous Chloride

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Hexane

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Hydrochloric Acid

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Hydrofluoric Acid

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Hydrofluorosilicic Acid

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Hydrogen Cyanide

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Hydrogen Peroxide

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Hydrofluoric Acid

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Isopropyl Acetate

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Liquid Argon

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Liquid Nitrogen

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Liquid Oxygen

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Maleic Anhydride

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Methanol

Methanol handling design & loading

Methyl Chloride

Methyl Chloride handling design & loading

Methyl Isocyanate

Methyl Isocyanate handling design & loading

Methyl Ethyl Ketone

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Methyl Methacrylate

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Molten Sulphur

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MDI

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Nitric Acid

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Oleum

Oleum handling design & loading

Phenol

Phenol handling design & loading

Phosphoric Acid

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Phosphorus Oxychloride

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Phosphorus Trichloride

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Polypropylene

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Renewable Diesel

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Sodium Cyanide

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Sodium Hypochlorite

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Sodium hydroxide

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Styrene Monomer

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Sulfuric Acid

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Sulfur Dioxide

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Titanium Tetrachloride

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Toluene

Toluene handling design & loading

Toluene Diisocyanate

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Turpentine

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UAN (Urea Ammonium Nitrate)

UAN handling design & loading

UREA

UREA handling design & loading

Vinyl Acetate

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Vinyl Chloride

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Xylene

Xylene handling design & loading

Zinc Chloride

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